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Vibrasie-opdragte 2 - Biologie

Vibrasie-opdragte 2 - Biologie


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Pr(-)Pr (Raman)Lumi-R(+)Lumi-R (Raman)Lumi-R* (Raman)Pfr (+)Pfr (Raman)Ek* (Raman)OpdragVerw
25572575(Cys, u (S-H))1
17361724( u (C_1=O))1,2,3,4,6
17381732(C_1=O)10,1
17351738(C_1=O)10
17341722(-COOH (Asp/Glu), u(C=O))1,2
1704( u (C_{19}=O))1,2,3,4,6
17201692(C_{19}=O)10,1
17161685(C_{19}=O)10
1692(amied I (lus/draai)/propionaat COOH, u (C=O))1
1687(amied I (lus/draai)/propionaat COOH, u (C=O))1
1683(amied I (lus/draai)/propionaat COOH, u (C=O))1
1672(amide I (lus/draai))1
1653(amied I (alfa -helikaal))1,2,3
1653(chromofoor^* delta (N-H))1
1653(chromofoor^* u (C-C))1,3,4
1631(amied I (eta-struktuur)/chromofoor u (C=C))1,3,5
1614(amied I (eta -struktuur)^* /chromofoor u (C=C))1,3,5
1606(amied I (eta -struktuur)^* /chromofoor u (C=C))1,3,4
1589(chromofoor u (C=C))1,3,4,6
16141609(C=C ek)11
15701554(amied II)1,3,4,5,7,8,9
1537(chromofoor u (C=C) + delta (N-H)/ u (C-N) + delta (N-H))1
14911512(chromofoor u (C=C) + delta (N-H)/ u (C-N) + delta (N-H))1
14871502(Trp, u (C-N) + delta (C-H) + delta (N-H))1
1246(chromofoor u (C-N))1
12441228

(Trp^* , u (C-C) + delta (C-H)/HisH, delta (CH_3) + u (C-N) + delta (N-H))

1
12231230(chromofoor u (C-N))1
1209(chromofoor u (C-C)/amino suur)1
11771172(chromofoor u (C-C)/amino suur)1
11511163(chromofoor u (C-N))1
1134(chromofoor u (C-N))1
1119(chromofoor u (C-N))1
1109(chromofoor u (C-N))1
11071099(SyH, u (C-N))1
10851082(chromofoor u (C-C)/amino suur)1
1072(chromofoor u (C-N))1
1345(C-C ,C-N rek)11
16521643(C_{15}=C_{16})10
16491633(C_{15}=C_{16})10
1629(C_{15}=C_{16} (metien brug) ,C_{17}=C_{18} (dubbel binding van die d ring))11
16521645(C_4=C_5 (A-B ring) rek)11
16331627(C_4=C_5)10
1632(C_4=C_5)10
1635(C_4=C_5)10
16111602(C_4=C_5, C_9=C_{10}, C_{10}=C_{11}, C_{15}=C_{16})10
794803816(viniel C_{15)-H waterstof buite-vlak (HOOP))11
12231056(viniel C-H in-vlak rock)11
1312(viniel N-H in-vlak rock)11
1566(in-fase in-vlak N-H rots (gelokaliseer na B en C ringe)11
15601570(N-H rock vir C en D ringe)11
1302(D-ring N-H rots)11
1302(N-H in-vlak rots)11
1112(viniel C-H rock)11
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  3. Siebert, F.; Grimm, R.; Rudiger, W.; Schmidt, G.; Scheer, H. EUR. J. Biochem. 1990, 194, 921.
  4. Foerstendorf, H.; Mummert, E.; Schafer, E.; Scheer, H.; Siebert, F. Biochemie 1996, 35, 10793.
  5. Andel, F., III; Murphy, J. T.; Haas, J. A.; McDowell, M. T.; van der Hoef, I.; Lugtenburg, J.; Lagarias, J. C.; Mathies, R.A. Biochemie 2000, 39, 2667.
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  7. Mroginski, M. A.; Murgida, D. H.; von Stetten, D.; Kneip, C.; Mark, F.; Hildebrandt, P. Am. Soc. 2004, 126, 16734.
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  10. van Thor, J. J.; Ronayne, K. L.; Towrie M. Soc. 2006, 129, 126
  11. Dasgupta J.; Frontiera R. R.; Taylor K. C.; Lagarias J. C.; Mathies R. PNAS 2009, 106, 1784


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